Effects of Homogeneous and Heterogeneous Mineralogy in Carbonate Acidizing
Keywords:
Carbonate acidizing, Coreflood experiment, Mineralogy heterogeneity, Wormhole geometryAbstract
A series of carbonate acidizing coreflood experiments using HCl was conducted on core samples from the Kujung Formation, offshore Northwest Java. Using XRD, SEM, and thin-section petrography, these samples were characterized as exhibiting varying degrees of heterogeneity. X-ray diffraction analysis showed that core plug Sample 7 consists of about 93% calcite, 3% dolomite, and 1–2% gypsum and pyrite, whereas core plug Sample 2 contains nearly 99% calcite. Mineralogical heterogeneity can affect the success of acidizing stimulation by determining the geometry (shape and size) of the wormholes that form. In addition to mineralogical heterogeneity, the presence of impurities in the rock may also influence the acidizing process and its outcomes. Conversely, in more homogeneous carbonate samples, a more uniform acid attack is observed. In homogeneous samples, carbonate dissolution was found to extensively “clean” clays and fine particles from the pore space. This study is expected to demonstrate different processes for enhancing permeability and porosity when using core samples of heterogeneous versus homogeneous mineralogy in carbonate acidizing applications.
References
Allen, T.O. & Roberts, A.P., 1993. Production operations. 5th ed. Tulsa, OK: OGCI Publications.
Barri, A.A., Al-Musabah, A.S., Al-Muntasheri, G.A. & Al-Ameri, S.S., 2015. Effect of stimulation with chelating agents on carbonate rocks integrity. In: SPE Middle East Oil & Gas Show and Conference. Manama, Bahrain: SPE. doi:10.2118/172709-MS.
Bazin, B. & Ben-Naceur, K., 1995. A laboratory evaluation of acid propagation in relation to acid fracturing: Results and interpretation. In: European Formation Damage Conference. The Hague, Netherlands: SPE. doi:10.2118/30085-MS.
Bazin, B., Roque, C. & Bouteca, M., 1996. Improvement in the characterization of acid wormholing by in situ X-ray CT visualizations. In: SPE International Symposium on Formation Damage Control. Lafayette, Louisiana: SPE. doi:10.2118/31073-MS.
Burton, R.C., Nozaki, M., Zwarich, N.R. & Furui, K., 2018. Improved understanding of acid wormholing in carbonate reservoirs through laboratory experiments and field measurements. In: SPE Annual Technical Conference and Exhibition. Dallas, Texas, USA: SPE. doi:10.2118/191625-MS.
Cohen, C.E., Barthel, F. & Ben-Naceur, K., 2007. A new matrix-acidizing simulator based on a large-scale dual-porosity approach. In: European Formation Damage Conference. Scheveningen, Netherlands: SPE. doi:10.2118/107755-MS.
De Oliveira, T.J.L., Schechter, D.S. & Pires, A.P., 2012. Numerical simulation of the acidizing process and PVBT extraction methodology including porosity/permeability and mineralogy heterogeneity. In: SPE International Symposium and Exhibition on Formation Damage Control. Lafayette, Louisiana: SPE. doi:10.2118/151823-MS.
Economides, M.J. & Nolte, K.G., 1989. Well analysis before and after fracture stimulation. In: The Centennial Symposium Petroleum Technology into the Second Century. Socorro, New Mexico: SPE. doi:10.2118/20153-MS.
Fedorov, K.M., Smirnov, A.S. & Kremieva, T.A., 2010. Carbonate acidizing: Conjunction of macro and micro scale investigations. In: Russian Oil & Gas Technical Conference and Exhibition. Moscow, Russia: SPE. doi:10.2118/136409-MS.
Fredd, C.N. & Fogler, H.S., 1996. The existence of an optimum Damkohler number for matrix stimulation of carbonate formations. In: SPE European Formation Damage Conference. The Hague, Netherlands: SPE. doi:10.2118/38167-MS.
Fredd, C.N. & Fogler, H.S., 2000a. Validation of carbonate matrix stimulation models. In: SPE International Symposium on Formation Damage Control. Lafayette, Louisiana: SPE. doi:10.2118/58713-MS.
Fredd, C.N. & Fogler, H.S., 2000b. Dynamic model of wormhole formation for effective skin reduction during carbonate matrix acidizing. In: SPE Permian Basin Oil and Gas Recovery Conference. Midland, Texas: SPE. doi:10.2118/59537-MS.
Gdanski, R., 2018. Formation mineralogy impacts scale inhibitor squeeze designs. In: SPE European/EAGE Annual Conference and Exhibition. Rome, Italy: SPE. doi:10.2118/113261-MS.
Ghalambor, A. & Economides, M.J., 2000. Formation damage abatement: A quarter century perspective. In: International Symposium on Formation Damage Control. Lafayette, Louisiana: SPE. doi:10.2118/58744-MS.
Glasbergen, G. & van den Akker, L., 2005. Field validation of acidizing wormhole models. In: SPE European Formation Damage Conference. Scheveningen, Netherlands: SPE. doi:10.2118/94695-MS.
Gong, M. & Yang, B., 1999. A quantitative model of wormholing process in carbonate acidizing. In: SPE Mid-Continent Operations Symposium. Oklahoma City, Oklahoma: SPE. doi:10.2118/52165-MS.
Kalfayan, L., 2008. Production enhancement with acid stimulation. Tulsa: PennWell.
Kalia, N. & Sarma, H.K., 2009. Wormhole formation in carbonates under varying temperature conditions. In: SPE European Formation Damage Conference. Scheveningen, Netherlands: SPE. doi:10.2118/121803-MS.
Klemin, D., Panga, M.K.R. & Valdes, J.R., 2015. Digital rock technology for quantitative prediction of acid stimulation efficiency in carbonates. In: SPE Annual Technical Conference and Exhibition. Houston, Texas: SPE. doi:10.2118/174807-MS.
Li, X., 2004. Rock texture and diagenetic evolution. Journal of Petroleum Science and Engineering, 42(1–2), pp.17–28.
Li, X. & Cheng, Y., 2004. Influence of rock texture on acidizing performance in carbonates. Journal of Petroleum Science and Engineering, 42(1–2), pp.29–40.
Lo, K.K. & Dean, R.H., 1989. Modelling of acid fracturing. SPE Journal, SPE-17110-PA.
Maheshwari, N., Maheshwari, A. & Sharma, M.M., 2013. 3-D simulation of carbonate acidization with HCl: Comparison with experiments. In: SPE Production and Operation Symposium. Oklahoma City, Oklahoma: SPE. doi:10.2118/164517-MS.
McDuff, D.R., Thompson, K.E. & Fogler, H.S., 2010. Understanding wormholes in carbonates: Unprecedented experimental scale and 3-D visualization. In: SPE Annual Technical Conference and Exhibition. Florence, Italy: SPE. doi:10.2118/134379-MS.
Morgenthaler, L.N., Zhu, D., Mou, J. & Hill, A.D., 2008. Effect of reservoir mineralogy and texture on acid response in heterogeneous sandstone. SPE Journal, SPE-102672-PA.
Muecke, T.W., 1982. Principles of acid stimulation. In: International Petroleum Exhibition and Technical Symposium of the Society of Petroleum Engineers. Beijing, China: SPE. doi:10.2118/10038-MS.
Navarette, R.C. & Lee, W.S., 1998. Laboratory and theoretical studies for acid fracture stimulation optimization. In: SPE Permian Basin Oil and Gas Recovery Conference. Midland, Texas: SPE. doi:10.2118/39776-MS.
Panga, M.K.R., Worley, J.B. & Fredd, C.N., 2004. A new model for predicting wormhole structure and formation in acid stimulation of carbonates. In: SPE International Symposium and Exhibition on Formation Damage Control. Lafayette, Louisiana: SPE. doi:10.2118/86517-MS.
Santosa, H. & Putra, R., 2018. Carbonate acidizing in Indonesian reservoirs. LEMIGAS Petroleum & Gas Bulletin, 52(2), pp.45–57.
Siregar, B. & Wibowo, S., 2019. Laboratory evaluation of acidizing fluid for Indonesian carbonate formations. LEMIGAS Petroleum & Gas Bulletin, 53(1), pp.12–25.
Settari, A., 1993. Modelling of acid-fracturing treatments. SPE Journal, SPE-21870-PA.
Shafiq, M.U., Ben Mahmud, H.K. & Arif, M., 2018. Mineralogy and pore topology analysis during matrix acidizing of tight sandstone and dolomite formations using chelating agents. Journal of Petroleum Science and Engineering, 171, pp.1126–1138. doi:10.1016/j.petrol.2018.09.027.
Wei, W., Varavei, A., Sanaei, A. & Sepehrnoori, K., 2019. Geochemical modeling of wormhole propagation in carbonate acidizing considering mineralogy heterogeneity. Scientific Contributions Oil & Gas, 47(3), pp.101–110. doi:10.1007/s13399-019-00569-8.
Xiao, J., Zhu, D., & Hill, A. D. (2019). Effect of heterogeneity in mineralogy distribution on acid fracturing efficiency. Scientific Contributions Oil & Gas, 47(3), 111–123. https://doi.org/10.1007/s13399-019-00570-5
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