Development and Fabrication of a Pressure Swing Adsorption System Using Molecular Sieve 13X for Integrated CO₂ Capture and Electrochemical Conversion

Mitra Eviani; Tirto Prakoso; Dadan Kusdiana; Pramujo Widiatmoko; Ida Bagus Oka Lyong Budhatama; Setyo Yanus Sasongko; Aryan Fathoni Amri; Wibawa Hendra Saputera; Hary Devianto

Authors

Mitra Eviani Ministry of Energy and Mineral Resources, Ciledug Raya Kav. 109, South Jakarta, 12230, Indonesia
Tirto Prakoso Department of Chemical Engineering, Bandung Institute of Technology, Ganesha no. 10, Bandung, West Java, 40132, Indonesia
Dadan Kusdiana Ministry of Energy and Mineral Resources, Ciledug Raya Kav. 109, South Jakarta, 12230, Indonesia
Pramujo Widiatmoko Bandung Institute of Technology
Ida Bagus Oka Lyong Budhatama Bandung Institute of Technology
Setyo Yanus Sasongko PT Aimtopindo Nuansa Kimia, Soekarno Hatta, Bandung
Aryan Fathoni Amri PT Aimtopindo Nuansa Kimia, Soekarno Hatta, Bandung
Wibawa Hendra Saputera Bandung Institute of Technology
Hary Devianto Department of Chemical Engineering, Bandung Institute of Technology, Ganesha no. 10, Bandung, West Java, 40132, Indonesia

Keywords:

CO2 capture, Pressure Swing Adsorption, gas adsorption, molecular sieve Zeolite 13X

Abstract

This study focuses on the development and performance evaluation of a Pressure Swing Adsorption (PSA) system utilizing molecular sieve Zeolite 13X for CO₂ capture. A fixed-bed reactor was designed and simulated with Aspen Adsorption to optimise adsorption conditions. The system, tested with a 24.75 L/min gas feed (10% CO₂, 90% N₂) at 30 °C and 6 bar, operated cyclically every 7 minutes. Simulation results recommended a reactor volume of 4.9 L (ID 102 mm × T/T 600 mm). Sensitivity analysis showed that adsorption capacity declined as CO₂concentration increased, with CO₂ uptake decreasing from 24.75 L/min at 10%-mol to 8.44 L/min at 70%-mol. Key design parameters such as feed flow rate, intraparticle voids, bulk density, and particle size were also evaluated. A prototype was built based on simulation results and tested, achieving a 120 s breakthrough time and an optimal 60 s swing interval over 17 cycles. This work supports the future integration of PSA-based CO₂ capture with electrochemical CO₂ reduction (ECO₂R).

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